Product ID:NICKEL-SAFE ICE MACHINE CLEANER
MSDS Date:04/11/1991
FSC:6850
NIIN:01-363-4770
MSDS Number: BPQZW

CALGON VESTAL LABORATORIES, DIV OF CALGON CORP

5035 MANCHESTER AVE
ST. LOUIS, MO 63100
US

Emergency Phone: 314-535-1810/800-424-9300(CHEMTREC)

Info Phone: 314-535-1395 (NIGHT)

Cage: 21667

CONVATEC, BRISTOL-MEYERS SQUIBB CO

147 ST. LOUIS, MO 63166-1096 US

Telephone: 314-535-1810 (DAY)

Cage: 21667

PHOSPHORIC ACID (SARA III)

CAS: 7664-38-2

RTECS: TB6300000

Fraction By Weight: < 30%

OSHA PEL 1 MG/M3/3 STEL

ACGIH TLV: 1 MG/M3/3 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CITRIC ACID

CAS: 77-92-9

RTECS: GE7350000

Fraction By Weight: < 5%

LD50 LC50 Mixture:TLV FOR PHOSPHORIC ACID IS 1 MG/M3.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE-EYE:CORROSIVE.MAY CAUSE SEVERE
IRRITATION,BURNS,PERMANENT TISSUE DAMAGE.SKIN:CORROSIVE.MAY CAUSE
SEVERE IRRITATION.NO IMMEDIATE BURNING SENSATIONS MAY BE
EXPECTED.INHALED:MAY CAUSE SEVERE RESPIR ATORY SYSTEM
IRRITATION.ORAL:CORROSIVE.MAY CAUSE SEVERE DIGESTIVE SYSTEM
IRRITATION & BURNS,TISSUE DAMAGE.CHRONIC-UNK.
Effects of Overexposure:CORROSIVE.MAY CAUSE SEVERE EYE
IRRITATION,BURNS,PERMANENT TISSUE DAMAGE.MAY CAUSE SEVERE SKIN
IRRITATION.NO IMMEDIATE BURNING SENSATIONS MAY BE EXPECTED.MAY
CAUSE SEVERE RESPIRATORY & DIGESTIVE SYSTEM S IRRITATION. SYMPTOMS
MAY INCLUDE MOUTH& THROAT PAIN, NAUSEA, VOMITING POSSIBLY WITH
FRESH BLOOD AND THIRST.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH PRE-EXISTING DISEASE INVOLVING THE RESPIRATORY TRACT MAY BE
AT INCREASED RISK FROM EXPOSURE.

First Aid:GET IMMEDIATE MEDICAL ATTENTION IN ALL CASES.EYE/SKIN:FLUSH
WITH WATER FOR 15 MINUTES.HOLD EYELIDS OPEN.INHALED:REMOVE TO FRESH
AIR & PROVIDE CPR IF NEEDED.ORAL:DO NOT INDUCE VOMITING.IF
CONSCIOUS,DRI NK 1-2 GLASSES OF WATER,MILK OR MILK OFMAGNESIA IF
POSSIBLE.GET IMMEDIATE MEDICAL HELP.

Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NO UNUSUAL FIRE AND/OR EXPLOSION HAZARDS.

Spill Release Procedures:WEAR PROTECTIVE GLOVES. MOP UP OR PICK UP WITH
SAND OR CLAY. NEUTRALIZE WITH SODA ASH. REQUIRES GOOD VENTILATION
AS CO2 IS PRODUCED. PLACE NEUTRALIZED SPILL IN DOT APPROVED
DISPOSAL CONTAINER. FLUSH R ESIDUES WITH LARGE AMOUNT OF WATER TO
DRAIN.
Neutralizing Agent:SODA ASH

Handling and Storage Precautions:STORAGE-STORE IN COOL,DRY AREA AWAY
FROM ALKALIES.KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. DO NOT GET IN EYES, ON
SKIN OR ON CLOTHING. AVOID BREATHING MISTS OR VAPORS. WASH
THOROUGHLY AFTER HANDLING.

Respiratory Protection:IF LEVELS EXCEED THE RECOMMENDED HEALTH
STANDARDS, WEAR A NIOSH-APPROVED VAPOR RESPIRATOR FOR ACID. FOR
EMERGENCY USE, WEAR A NIOSH APPROVED POSITIVE-PRESSURE MODE,
SELF-CONTAINED BREATHING APPARATUS (SCBA).
Ventilation:PROVIDE SUFFICIENT LOCAL EXHAUST VENTILATION TO CONTROL
INHALATION EXPOSURES BELOW OSHA'S PEL.
Protective Gloves:NEOPRENE OR RUBBER
Eye Protection:SAFETY GOGGLES & FACE SHIELD
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health

HCC:C1
Boiling Pt:>93.3C, 200.F
Melt/Freeze Pt:=-17.8C, 0.F
Spec Gravity:1.188
pH:<1
Solubility in Water:COMPLETE
Appearance and Odor:GREEN LIQUID - MILD CHEMICAL ODOR
Percent Volatiles by Volume:30

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES, AMMONIA, CHLORINE BLEACH
Stability Condition to Avoid:EXCESSIVE HEAT
Hazardous Decomposition Products:MAY FORM OXIDES OF PHOSPHORUS.

Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.